When a beginner starts playing Pokemon GO, player is not provided with these high tier Pokeballs. The balls are also not available in the Pokemon GO store. The reason behind this is that certain items are locked until the player reaches a certain level. Moreover, players will hardly find a Pokemon that is powerful enough that will require high tier balls.
Pokemon GO layers that hit level 12 will earn a reward of 20 Great Balls. At level 20, one will unlock Ultra Balls and at a still higher (unknown) level will unlock Master Balls. These Pokeballs will be available at PokeStops.
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